Development of experimental methods for measurements of vaporization enthalpies of ionic liquids [Elektronische Ressource] / vorgelegt von Ricardas Ralys

Development of experimental methods for measurements of vaporization enthalpies of ionic liquids [Elektronische Ressource] / vorgelegt von Ricardas Ralys

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amDevcelopmenhaftlsictgofFexpdererimengtalRicardasmethohstandsMatematiscforFmeasuremenersit?ttsvoflvvapgeborizationinencthalpies2011ofh-Nat?rwissenscIonichenLiquidsakult?tDissertationUnivzurRostoErlangungkdesorakeademiscehentGradesondoRalys,ctororenre26.08.1982rumKazacnaturaliumRosto(Dr.k,rer.ebruarnat.)1der Verteidigung 17 Mai 2011 [C mim] [Co(NCS) ]2 2 4tslotialwylimiv.olatile.comp.o.u.ndsliquids7.2.1.ClassicationTGAof.metho.ds.est-measuremen...s...bis.39.uartz.48.pressures.....ap.Results.....of...33.est-measuremen.treatmen...........ap8om2.2.Static.methoidazoliumdsap.1...56.tal...Measuremen.y.............ap.L.......t...ap...TGA-measuremen.37.........studies.imides..9.2.3.Boilingop1-aloinitwithmethth.o.d.(ebulliometry)of...rmination.y.4...and.....duction.57.........of.En.....289.2.4.T.ranspiration.me.th.o.d....3.3.1.of.en.reference...............Data.the.molecular.3.3.3.of.en.Ionic.3.3.4.of.of...Discussion........10.2.5.Langm.uir.metho3.4.1d1-alkyl-3-meth.sulfon...............V.TGA.en.l.bis.o.yl).uir.crobalance.d.............TGA.kyl-3-meth.....3.4.4.the12En2.6ofKn2udsentroeusiontenmetho53doutlo...........In.reaction.anning.Exp...............58.ts.V.orization.thalp..........143.32.7.Chromatographic.metho.d..............................33.T.ts.v.orization.thalpies.the.Molecular.iquids....16.2.8.Calorimetric.metho.ds..............3.3.2.treatmen.of.TGA-measuremen.of.liquids.33.T.ts.v.orization.thalpie.of.Liquids.35.Data.t.the.ts.ionic....173.43.Dev.elopmen.t.of.

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amDevcelopmenhaftlsictgofFexpdererimengtalRicardasmethohstandsMatematiscforFmeasuremenersit?ttsvoflvvapgeborizationinencthalpies2011ofh-Nat?rwissenscIonichenLiquidsakult?tDissertationUnivzurRostoErlangungkdesorakeademiscehentGradesondoRalys,ctororenre26.08.1982rumKazacnaturaliumRosto(Dr.k,rer.ebruarnat.)1der

Verteidigung 17 Mai 2011 [C mim] [Co(NCS) ]2 2 4
tslotialwylimiv.olatile.comp.o.u.ndsliquids7.2.1.ClassicationTGAof.metho.ds.est-measuremen...s...bis.39.uartz.48.pressures.....ap.Results.....of...33.est-measuremen.treatmen...........ap8om2.2.Static.methoidazoliumdsap.1...56.tal...Measuremen.y.............ap.L.......t...ap...TGA-measuremen.37.........studies.imides..9.2.3.Boilingop1-aloinitwithmethth.o.d.(ebulliometry)of...rmination.y.4...and.....duction.57.........of.En.....289.2.4.T.ranspiration.me.th.o.d....3.3.1.of.en.reference...............Data.the.molecular.3.3.3.of.en.Ionic.3.3.4.of.of...Discussion........10.2.5.Langm.uir.metho3.4.1d1-alkyl-3-meth.sulfon...............V.TGA.en.l.bis.o.yl).uir.crobalance.d.............TGA.kyl-3-meth.....3.4.4.the12En2.6ofKn2udsentroeusiontenmetho53doutlo...........In.reaction.anning.Exp...............58.ts.V.orization.thalp..........143.32.7.Chromatographic.metho.d..............................33.T.ts.v.orization.thalpies.the.Molecular.iquids....16.2.8.Calorimetric.metho.ds..............3.3.2.treatmen.of.TGA-measuremen.of.liquids.33.T.ts.v.orization.thalpie.of.Liquids.35.Data.t.the.ts.ionic....173.43.Dev.elopmen.t.of.the.screening.thermog.ra.vimetric.metho.d.for.a.quic.k.appraisal.of39enTGAthalpiesofofylimidazoliumv(triuoromethane-apyl)orisation.of.ILs.18.3.1.State.of.the.Art............3.4.2.alidation.f.v.orization.thalpies.ky.-3-meth.dazolium.(tr.u.r.ethanesulfon.imides.Langm.Q.Mi-.Me.o..............18.3.2.Exp.erimen.tal.section..3.4.3.studies.1-al.ylim.halides.......50.Dete.of.V.orization.thalp.ofdeterminationds.Metho.of.duction.In.tsofCon...................3.4.5.-.ok.conclusions..27.3.2.1.Materia.ls.and.c.hemicals....4.tro.to.dieren.sc.calorimetry.4.1.erimen.section........................27.3.2.2.TGA20 H (IL)f liq
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ofEnofthalp86y....F.tum.reaction...formation.........tum...98.IL...ann.in.the.........ciation.....con.....on....of584.1.3.Computations4.3.3.the.D.of.4.1.2.87.thalpies.Chemical.....4.4.1.........for.pair.......9.calculations.the.......4.4.4.thesis.ds65concl4.2.ResultsOutloand100discussionts.ng.......thalpies.ILs.state,.tial...En.of.gaseous.....Calculation.Phase.Reaction.Quan.culations............thalp....66.4.2.1.State.of.the.Art4.4.2.hemical.of.the.................4.4.3.hem.degree.ersion.syn...............thalp.IL.t.osite66.4.2.2DSCMsiolar.En.thalpies99ofandFwormation102of,IMeasuremenLsCalorimetryfrom.DSC-Measuremen.ts...70.4.2.3.I81ndEniofrectofDeterminationinofliquidMolariEnScthalpiesierenof.V.ap4.3.4orizationthalpiesofformationILsILs73the4.2.4state,V58ap.orization.En.thalp4.4yoffromGasEnEntofhalandpiesormation.oftumFCalormation.........of.Reaction..impro.emen.of.he88tEniza-yproformationedure......-.v.t.t.a.om74tion4.2.5cV.ap.orization.En.thalp.y.from.DSC.En.thalpies.of.Reac.tion,....89hemicalsQuanccandcalculations75degree4.3dissoStructureofionprop.ert.y.relationships.for.thermo.dynamic.prop.erties.of.ionic.liquids..Correlation.with.t.he.n6uQuanmcbicaleforrofofvC-atomsofinILthethesiscation.alkyl.c.hain.78.4.3.1.En.thalp.y.of.IL.syn.thesis.reaction,98rialsEneyattheMsyn4.1.1reac.i.Comp.Metho.....4.5.-.u.on............................80.4.3.25EnokthalpiesconclusionofthevorkapReferencesorization3of2
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