Metal complexes with non-innocent N-donor ligands [Elektronische Ressource] : molecular and electronic structures, reactivity, and application / vorgelegt von Marat M. Khusniyarov

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Metal Complexes with Non-innocent N-donor Ligands: Molecular and Electronic Structures, Reactivity, and ApplicationDissertationzurErlangung des Doktorgradesder Naturwissenschaften(Dr. rer. nat.)demFachbereich Chemieder Philipps-Universität Marburgvorgelegt vonMarat M. KhusniyarovausPetropawlowsk-KamtschatskiyRusslandMarburg an der Lahn2006Vom Fachbereich Chemieder Philipps-Universität Marburg als Dissertation am 09.06.2006 angenommen.Erstgutachter: Prof. Dr. J. SundermeyerZweitgutachter: Prof. Dr. M. BröringTag der mündlichen Prüfung am 30.06.2006to my wife MariaChemistry is just Physics of valence electronsArticles published: M. M. Khusniyarov, K. Harms, J. Sundermeyer; New Highly Fluorinated Phenazine Derivatives: Correlation between Crystal Structure and NMR Spectroscopy.J. Fluorine Chem. 2006, 127, 200– 204. M. M. Khusniyarov, K. Harms, O. Burghaus, J. Sundermeyer;Molecular and Electronic Structures of Homoleptic Nickel and Cobalt Complexes with Non-innocent Bulky Diimine Ligands Derived from Fluorinated 1,4-Diaza-1,3-butadien (DAD) and Bis(arylimino)acenaphthene (BIAN).Eur. J. Inorg. Chem. 2006, article online. M. M. Khusniyarov, K. Harms, J. Sundermeyer, B. Sarkar, W. Kaim, J. van Slageren, C.Duboc, J. Fiedler;A Series of Metal Complexes with the Non-Innocent N,N’-Bis(pentafluorophenyl)-o-phenylenediamine: Twisted Geometry as a Tuner for Electronic Structure.Manuscript in preparation.Report: M. M.

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Metal Complexes with Non-innocent
N-donor Ligands: Molecular and
Electronic Structures, Reactivity, and
Application
Dissertation
zur
Erlangung des Doktorgrades
der Naturwissenschaften
(Dr. rer. nat.)
dem
Fachbereich Chemie
der Philipps-Universität Marburg
vorgelegt von
Marat M. Khusniyarov
aus
Petropawlowsk-Kamtschatskiy
Russland
Marburg an der Lahn
2006Vom Fachbereich Chemie
der Philipps-Universität Marburg als Dissertation am 09.06.2006 angenommen.
Erstgutachter: Prof. Dr. J. Sundermeyer
Zweitgutachter: Prof. Dr. M. Bröring
Tag der mündlichen Prüfung am 30.06.2006to my wife MariaChemistry is just Physics
of valence electronsArticles published:
 M. M. Khusniyarov, K. Harms, J. Sundermeyer;
New Highly Fluorinated Phenazine Derivatives: Correlation between Crystal Structure and
NMR Spectroscopy.
J. Fluorine Chem. 2006, 127, 200– 204.
 M. M. Khusniyarov, K. Harms, O. Burghaus, J. Sundermeyer;
Molecular and Electronic Structures of Homoleptic Nickel and Cobalt Complexes with
Non-innocent Bulky Diimine Ligands Derived from Fluorinated 1,4-Diaza-1,3-butadien
(DAD) and Bis(arylimino)acenaphthene (BIAN).
Eur. J. Inorg. Chem. 2006, article online.
 M. M. Khusniyarov, K. Harms, J. Sundermeyer, B. Sarkar, W. Kaim, J. van Slageren, C.
Duboc, J. Fiedler;
A Series of Metal Complexes with the Non-Innocent N,N’-Bis(pentafluorophenyl)-o-
phenylenediamine: Twisted Geometry as a Tuner for Electronic Structure.
Manuscript in preparation.
Report:
 M. M. Khusniyarov;
Late Transition Metal Complexes with Non-innocent Nitrogen Ligands.
"Aktuelle Themen aus der Anorganischen Chemie", Fachbereich Chemie der Philipps-
thUniversität, Marburg, 9 February, 2006.
IAcknowledgements
I would like to acknowledge everyone who extended their support and help during the course of this
work. My deep sense of gratitude goes to:
 Prof. Dr. Jörg Sundermeyer for a great opportunity to perform my PhD work in his
research group and for this interesting research topic.
 Dr. Klaus Harms for all X-ray structures he determined.
 Gertraud Geiseler for her patience by searching for good crystals among dark powder in
dark solutions.
 Dr. Xiulan Xie for her interesting NMR lectures and for her help by my first steps on
working with NMR spectrometers.
 The whole NMR department for measurements of NMR spectra on high frequency
spectrometers and for assistance by my independent measurements.
 Dr. Olaf Burghaus for recording of EPR spectra, their simulation, and interesting
discussions about spins, ZFS, etc.
 P. Clemens for SQUID measurements and great interest in magnetic properties of my
complexes.
 Dr. Steinbach for his understanding of my problems regarding mass spectrometry and
help on working with MALDI spectrometer.
 The whole mass department for recording of numerous mass spectra for me.
 Prof. Dr. Martin Bröring for opportunity to perform UV-vis measurements at his research
group and for his consent to be the second referee for this work.
 Prof. Dr. Wolfgang Kaim and Dr. Biprajit Sarkar (Stuttgart University) for their interest
in part of the present work and fruitful collaboration (physicochemical investigation of
complexes in Chapter I).
 Alex Petrov for his introduction of synthetic chemistry to me and interesting discussions
about chemistry and more, as well as for a nice time in and outside the laboratory.
 Dr. Alexey Merkoulov for his fruitful discussions concerning physical chemistry and
spectroscopy.
 Irene Barth for her assistance in searching for every possible glasses, equipments, etc. in
our big laboratory.
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